| 受限介质中光化学反应的研究 |
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| 引用本文： | 吕锋锋,吴骊珠,张丽萍,佟振合,郑利强. 受限介质中光化学反应的研究[J]. 有机化学, 2006, 26(5): 599-609 |
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| 作者姓名： | 吕锋锋 吴骊珠 张丽萍 佟振合 郑利强 |
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| 作者单位： | 1. 中国科学院理化技术研究所,北京,100080
2. 山东大学胶体与界面化学教育部重点实验室,济南,250100 |
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| 基金项目： | 国家自然科学基金(Nos.20125207,20272066,20333080,20332040,20202013)，国家科技部“973”(No.2004CB719903)，中国科学院基础局资助项目. |
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| 摘 要： | 提高化学反应的选择性始终是化学家关注的热点. 本工作以光Fries重排反应、Norrish/Yang光环化反应、9-取代蒽衍生物的光二聚反应以及不对称光化学反应为例, 结合近年来在受限介质中光化学反应研究的最新进展, 总结了利用受限介质控制化学反应选择性的一般规律.
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| 关 键 词： | 受限介质 光反应 选择性 |
| 收稿时间： | 2005-07-12 |
| 修稿时间： | 2005-10-14 |
Recent Advances of Photochemical Reactions within the Confined Media |
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| L Feng-Feng,WU Li-Zhu,ZHANG Li-Ping,TUNG Chen-Ho,ZHENG Li-Qiang. Recent Advances of Photochemical Reactions within the Confined Media[J]. Chinese Journal of Organic Chemistry, 2006, 26(5): 599-609 |
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| Authors: | L Feng-Feng WU Li-Zhu ZHANG Li-Ping TUNG Chen-Ho ZHENG Li-Qiang |
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| Affiliation: | a Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101;b Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong Unuversity, Jinan 250100 |
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| Abstract: | The selectivity of the photochemical reactions is always an important concern of chemists. Herein the progress of photochemical reactions, including photo-fries rearrangements, Norrish/Yang photo- cyclization, dimerization of 9-substituted anthracenes and asymmetric photoreactions within the confined media is reviewed and the general rules are summarized for microreactor-controlled selectivity of the pho- tochemical transformations. |
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| Keywords: | confined media photoreaction selectivity |
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