Stable 17-electron manganese complexes in the synthesis of macromolecules |
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| Authors: | I. D. Grishin V. V. Krivykh A. A. Shchepalov E. S. Taits N. A. Ustynyuk D. F. Grishin |
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| Affiliation: | 1.Research Institute of Chemistry of the N. I. Lobachevsky Nizhny Novgorod State University,Nizhny Novgorod,Russian Federation;2.A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Moscow,Russian Federation |
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| Abstract: | Radical polymerization of methyl methacrylate and styrene in the presence of several cyclopentadienyl manganese dicarbonyl derivatives was studied. The influence of the molecular structure of the complexes on the molecular-weight characteristics of the macromolecules was estimated. Quantum chemical modeling of the initial polymerization step with participation of these complexes was performed. |
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