1,7-Palladium migration via C-H activation, followed by intramolecular amination: regioselective synthesis of benzotriazoles |
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Authors: | Zhou Jun He Jianjun Wang Binjie Yang Weijun Ren Hongjun |
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Institution: | Department of Chemistry, Zhejiang University, 38 Zheda Road, Hangzhou 310027, PR China. |
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Abstract: | A novel 1,7-palladium migration-cyclization-dealkylation sequence for the regioselective synthesis of benzotriazoles has been developed. These reactions proceed in excellent yields with high regioselectivities. The mechanism of the reaction has also been investigated. |
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