Induced fit interanion discrimination by binding-induced excimer formation |
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Authors: | Filby Maria H Dickson Sara Jane Zaccheroni Nelsi Prodi Luca Bonacchi Sara Montalti Marco Paterson Martin J Humphries Terry D Chiorboli Claudio Steed Jonathan W |
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Institution: | Department of Chemistry, Durham University, South Road, Durham, DH1 3LE, United Kingdom. |
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Abstract: | The synthesis, photophysical, and anion-binding properties of a series of di-, tri-, and tetrapodal anion-binding hosts based on aminopyridinium units with pyrenyl reporter groups are described. The ditopic mesitylene-derived calix4]arene-based host 4 binds strongly to dicarboxylates, particularly malonate, in a 2:1 anion:host ratio but is essentially nonemissive in the presence of all anions except chloride because of intramolecular quenching by the pyridinium units. Addition of chloride results in a conformational change, giving an initial increase in emission assigned to intramolecular excimer formation. Further chloride addition also results in an increase in the intensity of the pyrenyl monomer emission as chloride binding reduces the acceptor ability of the pyridinium groups. This behavior is not exhibited by control compounds 5 and 6, which lack the ditopic geometry and calixarene spacer unit; however, tripodal 6 forms 1:2 anion:host complexes with a range of anions. |
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