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Action of gaseous ammonia and water on neodymium diphthalocyanine
Authors:P N Moskalev  A I Sibilev
Institution:(1) B. P. Konstantinov St. Petersburg Institute of Nuclear Physics, Russian Academy of Sciences, 188350 Gatchina, Leningrad Region, Russian Federation
Abstract:The method of flow injection into the gas flow with detection of current resistance of the film was used to investigate the action of ammonia and water vapor on neodymium diphthalocyanine film. The value and sign of the electrophysical response are reversible at 18–22°C. When the film contacts with vapor, the current is changed within a few seconds, whereas the relaxation to the initial value when vapor is removed occurs within tens of seconds. The response parameters are suitable for developing effective sensors based on resistant films. No optical changes in the absorption spectra of the films were observed in the 400–800 nm region under the action of ammonia and water vapor. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1446–1447, July, 1998.
Keywords:phthalocyanine  neodymium  conductivity  ammonia  water  gas
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