| Asymmetric Synthesis and Crystal Structure of （-）-N-[（3R）-3-Cyclohexyl]-3-phenylpropananoyl]bornane-10,2-sultam |
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| 引用本文： | 曹秀芳,刘盛华. Asymmetric Synthesis and Crystal Structure of （-）-N-[（3R）-3-Cyclohexyl]-3-phenylpropananoyl]bornane-10,2-sultam[J]. 结构化学, 2011, 30(2): 202-205 |
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| 作者姓名： | 曹秀芳 刘盛华 |
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| 作者单位： | CAO Xiu-Fang(College of Science, Huazhong Agricultural University, Wuhan 430070, China);LIU Sheng-Hua(Key Laboratory of Pesticide and Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, China) |
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| 基金项目： | sponsored by the Science Foundation of Ministry of Education for the New Teacher at the University of China (No. 20070511006); the Research Initiation Funds of Huazhong Agricultural University (No. 52204-09057) |
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| 摘 要： | The title compound (-)-N-[(3R)-3-cyclohexyl]-3-phenylpropananoyl]bornane-10,2sultam (C 25 H 35 NO 3 S,M r=429.60),a derivative of camphorsultam,crystallizes in the monoclinic space group P2 1 /c with a=10.3301(7),b=19.4040(13),c=11.8106(8),β=100.5580(10)°,V=2327.3(3) 3,Z=4,D c=1.226 g/cm 3,λ=0.71073,μ(MoKα)=0.165 mm-1 and F(000)=928.X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat form (Fig.1).The planes constructed by (C(4),C(5),C(6),C(7)) and (C(7),C(8),C(9),C(4)) form a dihedral angle of 69.5°.The C(1)-C(2)-C(3) plane forms dihedral angles to the aforementioned planes of 89.8(1) and 85.9(3)°,respectively.And molecules are linked via hydrogen bonding (C-H···N/O) interactions.
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| 关 键 词： | 环己基 不对称合成 晶体结构 射线衍射分析 标题化合物 单斜晶系 平面形式 相互作用 |
Asymmetric Synthesis and Crystal Structure of (-)-N-[(3R)-3-Cyclohexyl]-3-phenylpropananoyl]bornane-10,2-sultam |
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| CAO Xiu-Fang,LIU Sheng-Hua. Asymmetric Synthesis and Crystal Structure of (-)-N-[(3R)-3-Cyclohexyl]-3-phenylpropananoyl]bornane-10,2-sultam[J]. Chinese Journal of Structural Chemistry, 2011, 30(2): 202-205 |
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| Authors: | CAO Xiu-Fang LIU Sheng-Hua |
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| Affiliation: | CAO Xiu-Fang a② LIU Sheng-Hua b a (College of Science,Huazhong Agricultural University,Wuhan 430070,China) b (Key Laboratory of Pesticide and Chemical Biology,Ministry of Education,College of Chemistry,Central China Normal University,Wuhan 430079,China) |
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| Abstract: | The title compound(-)-N-[(3R)-3-cyclohexyl]-3-phenylpropananoyl]bomane-10,2-sultam(C25H35NO3S,Mr=429.60),a derivative of camphorsultam, crystallizes in the monoclinic space group P21/c with a=10.3301(7),b=19.4040(13),c=11.8106(8)(A°),β= 100.5580(10)°,V=2327.3(3)(A°)3,Z=4,Dc=1.226 g/cm3,λ= 0.71073 (A°),μ(MoKa)=0.165 mm-1 and F(000)=928.X-ray diffraction analysis reveals that the six-membered ring of sultam shows a boat form(Fig.1).The planes constructed by(C(4),C(5),C(6),C(7))and(C(7),C(8),C(9),C(4))form a dihedral angle of 69.5°.The C(1)-C(2)-C(3)plane forms dihedral angles to the aforementioned planes of 89.8(1)and 85.9(3)°,respectively. And molecules are linked via hydrogen bonding(C-H…N/O)interactions. |
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| Keywords: | (-)-N-[(3R)-3-cyclohexyl]-3-phenylpropananoyl]bornane-10 2-sultam synthesis crystal structure |
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