Synthese und Eigenschaften von Bis(dialkylamino)-methylarsinen

Synthesis and Properties of Bis(dialkylamino)methylarsines The reactions of secondary amines with CH₃AsJ₂ lead to the formation of Bis(dialkylamino)methylarsines. Ten arsines have been prepared by this method and are described. IR and ¹H-NMR and mass spectral data are presented for these compounds and discussed. Acid molecules cleave the As? N bond. The reactions with halogen hydrides, water, alkoholes, thioles and amines are described.