Synthesis of Thioglycosides from Propargyl Glycosides Exploiting Alkynophilic Gold Catalyst |
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| Authors: | Srinivasa Rao Vidadala Shivaji A Thadke Srinivas Hotha Sudhir Kashyap |
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| Institution: | 1. Department of Chemistry , Indian Institute of Science Education &2. Research , Pune , 411 021 , India |
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| Abstract: | Various thioglycosides were synthesized from stable propargyl glycosides using catalytic quantity of AuBr3 and various thiol aglycons. The current protocol enables preparation of thioglycosides from propargyl glycosides in an efficient and simple manner. The reaction is fast, catalytic, and mild. Supplemental materials are available for this article. Go to the publisher's online edition of Journal of Carbohydrate Chemistry to view the free supplemental file. |
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| Keywords: | Glycosidation Thioglycoside Glycoconjugate Gold catalysis Oligosaccharide |
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