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Über das Auftreten von Monoselenan- und Monotelluran-disulfandiphosphonat bei der Umsetzung von SPO mit Seleno- und Telluropolythionaten
Authors:E Blasius  N Spannhake
Abstract:On the Formation of Monoselenane and Monotellurane Disulphane-diphosphonate by the Reaction of SPO urn:x-wiley:00442313:media:ZAAC19733990307:tex2gif-stack-5 with Seleno and Telluropolythionates In the reaction of seleno- and telluropolythionates with SPOurn:x-wiley:00442313:media:ZAAC19733990307:tex2gif-stack-6, SeS2P2Ourn:x-wiley:00442313:media:ZAAC19733990307:tex2gif-stack-7 and TeS2P2Ourn:x-wiley:00442313:media:ZAAC19733990307:tex2gif-stack-8 are formed and are described for the first time. Polysulfphane-diphosphonates, -disulphonates and -phosphonsulphonates occur as side and consecutive products. By evaluation of radiochemical double labelling with the nuclide pairs 35S? 32P and 35S? 75Se, it is possible to identify the products formed and obtain information about the reaction mechanism.
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