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Terminal Deoxy Hydroxyamino Sugars
Authors:Jean M J Tronchet  Guido Zosimo-landolfo  Nicoletta Bizzozero  Daniel Cabrini  Ford Habashi  Evelyne Jean
Institution:Institute of Pharmaceutical Chemistry , University of Geneva , 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland
Abstract:Abstract

Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information.
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