Terminal Deoxy Hydroxyamino Sugars |
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Authors: | Jean M J Tronchet Guido Zosimo-landolfo Nicoletta Bizzozero Daniel Cabrini Ford Habashi Evelyne Jean |
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Institution: | Institute of Pharmaceutical Chemistry , University of Geneva , 30 quai Ernest Ansermet, CH-1211, Geneva 4, Switzerland |
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Abstract: | Abstract Reduction of sugar aldoximes gave in good yield the corresponding terminal deoxy hydroxyamino sugars. These compounds were found to be reasonably stable (they could be kept for some weeks at 4° C). On standing in the air, these compounds in solution were spontaneously oxidized to the corresponding nitroxide free radicals whose ESR spectra gave useful structural information. |
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