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X-Ray Crystal Structure Determinations of Galactosylacetylene Building Blocks
Authors:David J. Leaver  Andrew B. Hughes  Anastasios Polyzos  Jonathan M. White
Affiliation:1. Department of Chemistry , La Trobe University , Melbourne, Victoria, 3086, Australia;2. CSIRO Materials Science and Engineering , Clayton South, Victoria, 3169, Australia;3. Department of Chemistry , University of Cambridge , Cambridge, CB2 1EW, United Kingdom;4. Bio21 Institute, School of Chemistry , University of Melbourne , Parkville, Victoria, 3010, Australia
Abstract:We report the crystal structures of two galactosylacetylenes: 3,7-anhydro-4,5,6,8-tetra-O-benzyl-1,1,2,2-tetradehydro-1,2-dideoxy-1-C-(trimethylsilyl)-D-glycero-L-mannooctitol (7) and 3,7-anhydro-4,5,6,8-tetra-O-benzyl-1,1,2,2-tetradehydro-1,2-D-glycero-L-mannooctitol (8). A short overview of the synthetic chemistry used to obtain these targets is mentioned.
Keywords:X-ray crystal structure  Galactosylacetylene  Structure  Synthesis
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