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Transport phenomena of sulfonated dyes into cellulose membrane: Effects of urea on parallel diffusion of mono azo dyes
Authors:M Maekawa  M Ohmori  A Yamashita  M Nango
Institution:(1) Division of Life Science and Human Technology Nara Women’s University Nara 630, Japan, JP;(2) Department of Applied Chemistry Nagoya Institute of Technology Showa-ku, Nagoya 466, Japan, JP
Abstract: Effects of urea on transport phenomena of sulfonated azo dyes with different aggregation constants into water-swollen cellulose membrane have been studied at 25–55 °C. The results were analyzed on the basis of a parallel transport theory of surface and pore diffusion. Addition of urea decreased equilibrium adsorption of the dyes onto cellulose and increased the surface and pore diffusivities for the parallel diffusion model of the dye with high aggreg-ation constant. Temperature dependence of the effects was also discussed. Received: 30 November 1996 Accepted: 7 April 1997
Keywords:  Sulfonated dye  cellulose membrane  urea  parallel transport theory  aggregation constant
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