An iron(III) complex salt containing pyrazole as both ligand and counter‐ion: bis(1H‐pyrazol‐2‐ium) pentacyanido(1H‐pyrazole‐κN2)ferrate(III)期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

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An iron(III) complex salt containing pyrazole as both ligand and counter‐ion: bis(1H‐pyrazol‐2‐ium) pentacyanido(1H‐pyrazole‐κN2)ferrate(III)

Authors:	Yu‐Feng Wang Chun‐Hua Yu Run‐Qiang Zhu

Abstract:	The title compound, (C₃H₅N₂)₂Fe(CN)₅(C₃H₄N₂)], is composed of a mononuclear Fe(CN)₅(pyrazole)]^2? dianion and two 1H‐pyrazol‐2‐ium cations. A three‐dimensional supramolecular network is formed through a rich scheme of N—H...N hydrogen bonds and C—H...π interactions among the cations and anions.

Keywords:	crystal structure iron(III) cation cyanide ligands pyrazole ligands pentacyanido(pyrazole)ferrate(III) hydrogen bonding three‐dimensional supramolecular network