A three‐dimensional cadmium(II) coordination polymer: poly[[[μ‐4,4′‐(propane‐1,3‐diyl)dipyridine‐κ2N:N](μ‐3,3′‐thiodipropionato‐κ3O,O′:O)cadmium(II)] monohydrate] |
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Authors: | Xiao‐Min Hao Gang Chen Chang‐Sheng Gu Ji‐Wei Liu |
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Abstract: | In the title coordination polymer, {[Cd(C6H8O4S)(C13H14N2)]·H2O}n, the CdII atom displays a distorted octahedral coordination, formed by three carboxylate O atoms and one S atom from three different 3,3′‐thiodipropionate ligands, and two N atoms from two different 4,4′‐(propane‐1,3‐diyl)dipyridine ligands. The CdII centres are bridged through carboxylate O atoms of 3,3′‐thiodipropionate ligands and through N atoms of 4,4′‐(propane‐1,3‐diyl)dipyridine ligands to form two different one‐dimensional chains, which intersect to form a two‐dimensional layer. These two‐dimensional layers are linked by S atoms of 3,3′‐thiodipropionate ligands from adjacent layers to form a three‐dimensional network. |
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Keywords: | crystal structure CdII complex 4,4′ ‐(propane‐1,3‐diyl)dipyridine 3,3′ ‐thiodipropionate three‐dimensional coordination polymer |
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