Abstract: | In catena‐polyaqua1,3‐bis(pyridine‐3‐ylmethoxy)benzene‐κN]zinc(II)]‐μ2‐benzene‐1,4‐dicarboxylato‐κ2O1:O4], Zn(C8H4O4)(C18H16N2O2)(H2O)]n, each ZnII centre is tetrahedrally coordinated by two O atoms of bridging carboxylate groups from two benzene‐1,4‐dicarboxylate anions (denoted L2?), one O atom from a water molecule and one N atom from a 1,3‐bis(pyridin‐3‐yl)methoxy]benzene ligand (denoted bpmb). (Aqua)O—H...N hydrogen‐bonding interactions induce the formation of one‐dimensional helical Zn(L)(bpmb)(H2O)]n chains which are interlinked through (aqua)O—H...O hydrogen‐bonding interactions, producing two‐dimensional corrugated sheets. |