Facile insertion reaction of arynes into carbon-carbon sigma-bonds |
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| Authors: | Yoshida Hiroto Watanabe Masahiko Ohshita Joji Kunai Atsutaka |
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| Affiliation: | Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan. yhiroto@hiroshima-u.ac.jp |
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| Abstract: | The carbon-carbon sigma-bond of various beta-dicarbonyl compounds was found to add to the triple bond of arynes under extremely mild conditions, leading to direct introduction of different carbon functional groups into the aromatic skeletons. |
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