| CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides |
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| 作者姓名： | Ye Feng WANG Yuan ZHOU Jia Rui WANG Lei LIU Qing Xiang GUO |
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| 作者单位： | Ye Feng WANG，Yuan ZHOU，Jia Rui WANG，Lei LIU，Qing Xiang GUO Department of Chemistry，University of Science and Technology of China，Hefei 230026 |
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| 摘 要： | Aryl thiocyanates are important compounds not only for their interesting biological properties, but also because of their use as a versatile starting material for many sulfur- containing aromatic compounds, including sulfonyl cyanides, sulfonic acids, sul…
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| 关 键 词： | 碘化铜催化剂 合成 交叉耦合反应 芳基硫氰酸酯 芳基碘化物 1 10-邻二氮杂菲 |
| 收稿时间： | 03 6 2006 12:00AM |
CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides |
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| Ye Feng WANG Yuan ZHOU Jia Rui WANG Lei LIU Qing Xiang GUO.CuI-catalyzed Synthesis of Aryl Thiocyanates from Aryl Iodides[J].Chinese Chemical Letters,2006,17(10):1283-1286. |
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| Authors: | Ye Feng WANG Yuan ZHOU Jia Rui WANG Lei LIU Qing Xiang GUO |
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| Abstract: | An operationally simple and inexpensive catalyst system was developed for the cross coupling of potassium thiocyanate with aryl iodides by using CuI as catalyst, 1, 10-phenanthroline as ligand, and tetraethylammonium iodide as activator. The procedure is applicable for the synthesis of diverse aryl thiocyanates without any exotic, poisonous reagents. |
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| Keywords: | Cross coupling reaction CuI aryl thiocyanate aryl iodide 1 10-phenanthroline |
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