Preparation of Some Benzyl D-Glucuronatesfrom 4-Methoxybenzylidene Derivatives of D-Glucuronic Acid |
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Authors: | Monika Poláková Du?an Joniak Miloslav ?uri? |
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Affiliation: | (1) Laboratory of Microbiology, Wageningen University, Dreijenplein 10, 6703, HB, Wageningen, The Netherlands |
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Abstract: | Because of the low stability of the benzyl ester linkage in benzyl 1,2:3,5-di-O-benzylidene-α-D-glucofuranuronate during the removal of the benzylidene groups by acid hydrolysis and/or hydrogenolysis, 4-methoxybenzylidene groups were used to block the free hydroxyl groups of D-glucuronic acid. Several benzyl esters of D-glucuronic acid were prepared, and their relative rates of acid catalyzed hydrolysis were determined by liquid-chromatographic separation of the reaction mixture and subsequent diode array detection. |
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