Porphyrins and their derivatives: XXVI. Synthesis and properties of 2-(3-butenyl)-5,10,15,20-tetraphenylporphyrin |
| |
Authors: | Berezovskii V. V. Ishkov Yu. V. Mazepa A. V. |
| |
Affiliation: | 1.Mechnikov Odessa National University, Odessa, 65026, Ukraine ; |
| |
Abstract: | 2-[2-(1,3-Dioxolan-2-yl)vinyl]-5,10,15,20-tetraphenylporphyrin and its copper complex were reduced into the corresponding ethyldioxolanes by diimide generated in the system hydrazine hydrate — air oxygen — pyridine. The hydrolysis of the obtained ethyldioxolanes results in the formylethyl derivatives that react with the methylenetriphenylphosphorane to form 2-(3-butenyl)-5,10,15,20-tetraphenyl porphyrin and its copper complex. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|