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Copper iodide-catalyzed cyclization of (Z)-chalcogenoenynes
Authors:Stein André L  Alves Diego  da Rocha Juliana T  Nogueira Cristina W  Zeni Gilson
Affiliation:Laboratório de Síntese, Reatividade, Avalia??o, Toxicológica e Farmacológica de Organocalcogenios-CCNE-UFSM, 97105-900-Santa Maria, RS, Brazil.
Abstract:We present here our results of the efficient copper-catalyzed cyclizations of chalcogenoenynes and establish a route to obtain 3-substituted chalcogenophenes in good to excellent yields. In addition, the obtained chalcogenophenes were readily transformed to more complex products using the palladium-catalyzed cross-coupling reactions with boronic acids to give Suzuki-type products in good yields.
Keywords:
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