| Syntheses and Crystal Structures of One-dimensional Ni（Ⅱ） Complexes with 5-Tert-butyl Isophthalic Acid |
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| 作者姓名： | FAN Yao-Ting ;LI Bo ;bMA Lu-Fang ;WANG Li-Ya |
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| 作者单位： | FAN Yao-Ting(Department of Chemistry, Zhengzhou University, Zhengzhou 450001, China);LI Bo(Department of Chemistry, Zhengzhou University, Zhengzhou 450001, China;College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China);MA Lu-Fang,WANG Li-Ya(College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China) |
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| 基金项目： | the National Natural Science Foundation of China，the Henan Tackle Key Problem of Science and Technology，the Foundation of Education Committee of Henan Province |
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| 摘 要： | Two new Ni（ Ⅱ） coordination polymers, {Ni（tbip）（bipy）（H2O）]-0.5H2O}n 1 and Ni（tbip）（phen）（H2O）]n 2 （Hatbip = 5-tert-butyl isophthalic acid, bipy = 2,2＇-bipyridine, phen = 1,10-phenanthroline）, have been synthesized under hydrothermal conditions and characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. In the two polymers, H2tbip acts as a tridentate ligand. Compound 1 has a tbip bridged 1-D linear chain which is extended by hydrogen bonds into a 1-D double chain, while compound 2 exhibits a 1-D zigzag chain.
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| 关 键 词： | 间苯二甲酸 叔丁基 一维 晶体结构 合成 配合物 配位聚合物 X射线衍射 |
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