Unsymmetrical Pentoxy-Substituted Porphyrazines |
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Authors: | I. Yu. Nikolaev E. V. Kudrik V. P. Kulinich G. P. Shaposhnikov |
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Affiliation: | (1) Ivanovo State University of Chemical Technology, Ivanovo, Russia |
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Abstract: | The reactions of 3,6-dipentoxyphthalonitrile (A) in the 1-pentanol - magnesium pentylate medium with phthalonitrile, 2,3-di(methylsulfanyl)-2-butenedinitrile, and 2,3-dihydro-1,4-dithiin-5,6-dicarbonitrile (B) were performed. Unsymmetrically substituted porphyrazines A3B were prepared and studied. The influence of the structure of fragment B on the spectral characteristics of the porphyrazines was examined.__________Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 3, 2005, pp. 504–508.Original Russian Text Copyright © 2005 by Nikolaev, Kudrik, Kulinich, Shaposhnikov. |
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