Kinetics and mechanism of the furan peroxide formation in the reaction of furfural with hydrogen peroxide in the presence or absence of sodium molybdate |
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Authors: | E. P. Grunskaya L. A. Badovskaya T. Ya. Kaklyugina V. V. Poskonin |
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Affiliation: | (1) Kuban State Technological University, Krasnodar, Russia |
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Abstract: | The kinetics of the initial stage of the furfural reaction with hydrogen peroxide was studied in water in the presence of Na2MoO4 and in n-butanol without a catalyst. The mechanisms of furfural conversion in the Na2MoO4-H2O2 system and oxidation by hydrogen peroxide in the absence of sodium molybdate are discussed. Based on kinetic studies, the mechanism of furan peroxide formation is proposed. Proceedings of X International Conference on Chemistry of Organic and Organoelement Peroxides (Moscow, June 16–18, 1998). |
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