First and Highly Diastereoselective Synthesis of Palladepanes |
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| Authors: | Hashmi Rivas Nass A Bats Bolte |
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| Affiliation: | Institut für Organische Chemie der Universit?t, Marie-Curie-Strasse 11, D-60439 Frankfurt (Germany). |
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| Abstract: | Unexpected stability is observed for the palladacycloheptane rac-2, which is obtained as major product and single diastereomer from the cyclization of 1 and Pd(0). Up to a temperature of 50 degrees C 2 shows neither reductive elimination nor intramolecular insertion of another olefin. |
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