1,3-丙二醇制备研究进展 |
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引用本文: | 吴从意.1,3-丙二醇制备研究进展[J].分子催化,2012,26(3):276-283. |
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作者姓名: | 吴从意 |
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作者单位: | 1. 中国科学院兰州化学物埋研究所羰基合成与选择氧化国家重点实验室,甘肃兰州730000 中国科学院研究生院,北京100049 2. 中国科学院兰州化学物埋研究所羰基合成与选择氧化国家重点实验室,甘肃兰州,730000 |
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基金项目: | 国家自然科学基金项目(面上项目,重点项目,重大项目) |
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摘 要: | 1,3丙二醇(1,3-PDO)是一种重要的化工原料,可以作为溶剂、抗冻剂、增塑剂、乳化剂、防腐剂、洗涤剂和润滑剂等1],在食品、医药、化妆品和有机合成中有着重要应用.此外,1,3-PDO还可以作为聚酯、聚醚和聚氨酯的单体.
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关 键 词: | 1 3-丙二醇 3-羟基丙醛 发酵法 甘油 加氢 |
收稿时间: | 2012/3/29 0:00:00 |
修稿时间: | 2012/4/25 0:00:00 |
Progress in the Synthesis of 1,3-Propanediol |
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Institution: | Lanzhou Institute of Chemical Physics Chinese Academy of Sciences |
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Abstract: | As an important chemical raw materials, 1,3-propanediol has been paid ever increasing attention, and much effort has been made. In addition to classical preparation methods such as hydration of acrolein, hydroformylation of ethylene oxide to 3-hydroxypropanal followed by hydrogenation, and the fermentation of polyol by microbial to 1,3-propanediol, hydrogenation of methyl 3-hydroxypropionate and selective hydrogenolysis of glycerol to 1,3-propanediol as novel alternative routes has been focus. In this paper, the present status and research advances on preparation of 1,3-propanediol were reviewed. Moreover, the development trends and future were also discussed based on the previous work. |
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Keywords: | 1 3-propanediol 3-hydroxypropanal fermentation glycerol hydrogenation |
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