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A novel polymeric membrane electrode for the potentiometric analysis of Cu in drinking water
Authors:Zsófia Szigeti  Klára Tóth  Daniel J Fliegel  Ernö Pretsch
Institution:a Laboratorium für Organische Chemie, ETH Hönggerberg, CH-8093 Zürich, Switzerland
b Department of Organic Chemical Technology, Budapest University of Technology and Economics, Szt. Gellért tér 4, H 1111 Budapest, Hungary
c Research Group for Technical Analytical Chemistry of the Hungarian Academy of Sciences, Institute of General and Analytical Chemistry, Budapest University of Technology and Economics, Szt. Gellért tér 4, H 1111 Budapest, Hungary
d Laboratorium für Anorganische Chemie, ETH Hönggerberg, CH 8093 Zürich, Switzerland
Abstract:Based on a novel ionophore, an ion-selective electrode has been developed for the determination of Cu2+ in drinking water. Its selectivity behavior is characterized and its lower detection limit optimized for measurements with different electrolyte backgrounds. The lower detection limit was 2 × 10−9 M Cu2+ for samples with low ionic background and 1 × 10−7 M Cu2+ with ionic background typically found in drinking water.
Keywords:Potentiometric sensor  ICP-MS  Copper determination  Drinking water
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