From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn4(H2O)18WZnMn2(H2O)2(ZnW9O34)2]4- |
| |
Authors: | Shi Lian-Xu Zhao Wen-Feng Xu Xuan Tang Jing Wu Chuan-De |
| |
Affiliation: | Department of Chemistry, Zhejiang University, Hangzhou 310027, People's Republic of China. |
| |
Abstract: | A 1D anionic polyoxometalate, [Mn(4)(H(2)O)(18)WZnMn(2)(H(2)O)(2)(ZnW(9)O(34))(2)](4-), undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co(2+) and Cu(2+)) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1,4-dihydropyridines that is dependent on the inserted heterogeneous metal cations. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|