Asymmetric synthesis of S-5-benzyloxytryptophan,S-α-allylglycine and S-β-(2-naphthyl)alanine |
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Authors: | Yu N Belokon' N I Chernoglazova E V Ivanova A N Popkov M B Saporovskaya N N Suvorov V M Belikov |
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Institution: | (1) A. N. Nesmyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The synthesis of optically pure S-5-benzyloxytryptophan, S- -(2-naphthyl)alanine, and S- -allylglycine was carried out by alkylating glycine in the Ni(II) complex of its Schiff base with S-2-N-(N -benzylpropyl)aminobenzophenone, followed by Chromatographic separation of the mixture of diastereomeric alkylated complexes.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2818–2821, December, 1988. |
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