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Calyciphyllines H-M, new Daphniphyllum alkaloids from Daphniphyllum calycinum
Authors:Shizuka Saito  Takaaki Kubota  Norimichi Nakahata
Institution:a Graduate School of Pharmaceutical Sciences, Hokkaido University, Sapporo 060-0812, Japan
b Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
Abstract:Six new Daphniphyllum alkaloids, calyciphyllines H-M (1-6), were isolated from the leaves and stems of Daphniphyllum calycinum (Daphniphyllaceae). The structures and relative stereochemistry of 1-6 were elucidated on the basis of spectroscopic data, and the absolute stereochemistry of 3 was assigned by PGME method.
Keywords:Daphniphyllum calycinum  Daphniphyllum alkaloid  Calyciphyllines H-M
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