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One-pot synthesis of substituted 3-amino-2-nitrothiophenes and selenophenes |
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| Authors: | David Thomae Gilbert Kirsch Pierre Seck |
| Affiliation: | a Laboratoire d'Ingénierie Moléculaire et Biochimie Pharmacologique, Institut Jean Barriol, FR CNRS 2843, 1 Boulevard Arago, 57070 METZ, France b Laboratoire de Chimie, Faculté des Sciences, de la Technologie et de la Communication, Université du Luxembourg, 162a, avenue de la Faïencerie, L-1511 Luxembourg, Luxembourg |
| Abstract: | In this work, we described an easy preparation of substituted 3-amino-2-nitrothiophenes and selenophenes. Substituted β-chloroacrylonitriles were reacted with sodium sulfide or sodium selenide and bromonitromethane to yield the expected compounds in a one-pot three-step procedure in good yields. |
| Keywords: | 3-Amino-2-nitrothiophenes 3-Amino-2-nitroselenophenes Bromonitromethane Substituted β-chloroacrylonitriles |
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