Chiral Phebox-rhodium complexes as catalysts for asymmetric direct aldol reaction |
| |
| Authors: | Hiroko Inoue |
| |
| Institution: | Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan |
| |
| Abstract: | Chiral bis(oxazolinyl)phenyl-rhodium complexes act as catalysts in the combination of AgOTf for direct aldol reaction of ketones and aromatic aldehydes to give the corresponding β-hydroxyketones in high anti-selectivity and a good to high enantioselectivity up to 91% ee. |
| |
| Keywords: | Rhodium Asymmetric catalysis Direct aldol reaction Bisoxazoline |
| 本文献已被 ScienceDirect 等数据库收录！ |
