Tandem annulation strategy for the convergent synthesis of benzonaphthopyranones: total synthesis of chartarin and O-methylhayumicinone |
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Authors: | Sutapa Ray |
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Affiliation: | Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India |
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Abstract: | A Hauser-initiated tandem annulation has been developed for the rapid regiospecific synthesis of benzonaphthopyranones via formation of two rings in one-pot operation. This strategy has been generalized with benzonaphthopyranones 26, 29, 32, and 35. It has also been employed in a short synthesis of chartarin (3) and O-methylhayumicinone (67). |
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Keywords: | Hauser annulation Benzonaphthopyranone Chartreusin Chrymutasin Hayumicin |
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