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Non-radiative decay and mode mixing in benzene
Institution:1. Ministry of Education Key Laboratory of Analysis and Detection for Food Safety, Fujian Provincial Key Laboratory of Analysis and Detection for Food Safety, College of Chemistry, Fuzhou University, Fuzhou, Fujian 350002, China;2. Testing Center, The Sport Science Research Center, Fuzhou University, Fuzhou, Fujian 350002, China;3. Environmental monitoring center of Fujian province, Fuzhou, Fujian 350003, China;1. Division of Soil Science and Environment, Department of Plant Science and Natural Resources, Faculty of Agriculture, Khon Kaen University, Khon Kaen, 40002, Thailand;2. Research Group of Soil Organic Matter Management and Problem Soils in Northeast Thailand, Khon Kaen University, Khon Kaen, 40002, Thailand;3. Department of Soil Science, Faculty of Agriculture, Kasetsart University, Bangkok, 10900, Thailand;4. School of Agriculture and Environment, The University of Western Australia, 35 Stirling Highway, Crawley, WA 6009, Australia;1. Department of Chemistry and Chemical Biology, Gunma University, Kiryu, Gunma 376-8515, Japan;2. Department of Chemistry and Materials Science, Gunma National College of Technology, Maebashi, Gunma 371-8530, Japan;1. Coordenadoria de Química e Biologia, IFES, Campus Vitória-ES, 29040-780, Brazil;2. Departamento de Química, UFMG, Belo Horizonte, MG 31270-901, Brazil;3. Departamento de Farmácia, UFJF, Campus Governador Valadares-MG, 35010-177, Brazil
Abstract:The non-radiative decay of mixed vibronic states is studied using the Fermi resonance 62l0−112 states in S1 benzene as a prototype. A strong dependence on the mixing coefficient is exhibited, and the results are compared with the experimental data of Stephenson et al. to elucidate the nature of the mixed state.
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