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Two-color multiphoton ionization spectra of jet-cooled p-difluorobenzene - s and d Rydberg states
Institution:1. Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology, 4259-R1-15, Nagatsuta-cho, Midori-ku, Yokohama 226-8503, Japan;2. Institut für Optik und Atomare Physik, Technische Universität Berlin, Hardenbergstr. 36, 10623 Berlin, Germany;1. Department of Materials Science and Engineering, National Cheng Kung University, Tainan, Taiwan;2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen, China;3. Precision and Intelligence Laboratory, Tokyo Institute of Technology, Yokohama, Japan;1. Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, Republic of Korea;2. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259, Nagatsuta-cho, Midori-ku, Yokohama, Japan;1. Department of Chemical Engineering, National Tsing Hua University, 101, Section 2, Kuang-Fu Road, Hsin-Chu 30013 Taiwan;2. Precision and Intelligence Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama, Kanagawa 226-8503, Japan
Abstract:Two-color multiphoton ionization spectra of jet-cooled p-difluorobenzene due to the transitions from S1 state to highly excited Rydberg states have been observed. At least six different Rydberg series of s and d characters were found. The results indicate a reduction of molecular symmetry in the Rydberg state to C2h. The Rydberg states belonging to different series exhibit different ionization behavior.
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