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Raman probing of overtone and combination bands to study the vibrational energy distribution produced by multiple-photon excitation
Affiliation:1. School of Electronic and Information, Qingdao University, Qingdao 266071, China;2. School of Physics, Qingdao University, Qingdao 266071, China;3. College of Physics and Electronic Information, Dezhou University, China;1. Department of Electronic Engineering, Chang Gung University, Taiwan;2. Department of Nephrology, Chang Gung Memorial Hospital, Taiwan;3. Biomedical Engineering Research Center, Chang Gung University, Taiwan;4. Department of Materials Engineering, Ming Chi University of Technology, Taiwan;1. School of Material Science and Engineering, Nanchang University, Nanchang 330031, China;2. National Institute of LED on Si Substrate, Nanchang University, Nanchang 330047, China
Abstract:Vibrational energy distribution in CF3Br, produced by multiple-photon excitation, is studied with the use of Raman probing of fundamental bands and also overtone and combinations bands. On a collision-free time scale, statistical energy distribution among vibrational modes is found at energies over 7200 cm−1. Possible physical causes of this effect are discussed.
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