Photodissociation channels for pentafluorochlorobenzene excited at 193 nm in molecular beams |
| |
| Affiliation: | 1. Department of Chemistry and Biochemistry, California State University Northridge, Northridge, CA 91330-8262, United States;2. Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen Ø, Denmark;1. Department of Chemistry, University of Copenhagen, 5 Universitetsparken, 2100, Copenhagen Ø, Denmark;2. Department of Chemistry and Biochemistry, California State University Northridge, Northridge, CA, 91330-8262, United States |
| |
| Abstract: | A molecular beam of C6F5Cl was photolyzed using an excimer laser at 193 nm. Measurements of time-of-flight distributions of the Cl photofragment revealed a prominent fluorination effect on the dissociation process, namely a large reduction of the kinetic energy of the fragments. The dominant process is dissociation after thermalization to the ground state. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
