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13C NMR spectra of liquid crystalline substances in the isotropic,nematic and solid phases
Affiliation:1. Department of Chemistry, Chung-Ang University, Seoul 06974, South Korea;2. Division of Chemical and Medical Metrology, Korea Research Institute of Standards and Science, Yuseong, Daejeon 34113, South Korea
Abstract:A CP MAS 13C NMR spectrum indicates that some liquid crystalline substances containing both cyclohexane and benzene rings have a local molecular motion around the benzene plane in the solid state, and the cyclohexane ring has a rigid conformation. The reorientational diffusion of the whole molecule is also observed in the solid state.
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