IR laser chemistry in SO2. photo-oxidation of CO |
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Institution: | Laboratoire de Chimie Générate, Equipe de Recherches Associée du CNRS UA 870, Vnmersité P. et M. Curie, 4 Place Jussieu, 75230 Paris Cedex 05, France |
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Abstract: | By using a cw tunable CO2 laser, a bimolecular reaction can be induced in a binary SO2-CO gas mixture with one reactant (SO2) as photoabsorbing species. The participation of a metastable triplet state of SO2 responsible for the CO photo-oxidation is demonstrated and the minimum overall internal free energy of the reaction is estimated. |
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