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One-electron relativistic molecules with Coulomb interaction
Authors:Ingrid Daubechies  Elliott H. Lieb
Affiliation:1. Departments of Mathematics and Physics, Princeton University, 08544, Princeton, NJ, USA
Abstract:As an approximation to a relativistic one-electron molecule, we study the operator (H = ( - Delta + m^2 )^{1/2} - e^2 sumlimits_{j = 1}^K {Z_j } |x - R_j |^{ - 1}) withZ j ≧0,e ?2=137.04.H is bounded below if and only ife 2 Z j ≦2/π allj. Assuming this condition, the system is unstable whene 2Z j >2/π in the sense thatE 0=inf spec(H)→?∞ as the R j →0, allj. We prove that the nuclear Coulomb repulsion more than restores stability; namely (E_0 + 0.069e^2 sumlimits_{i< j} {Z_i Z_j } |R_i - R_j |^{ - 1} geqq 0) . We also show thatE 0 is an increasing function of the internuclear distances |R i ?R j |.
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