One-electron relativistic molecules with Coulomb interaction |
| |
Authors: | Ingrid Daubechies Elliott H. Lieb |
| |
Affiliation: | 1. Departments of Mathematics and Physics, Princeton University, 08544, Princeton, NJ, USA
|
| |
Abstract: | As an approximation to a relativistic one-electron molecule, we study the operator (H = ( - Delta + m^2 )^{1/2} - e^2 sumlimits_{j = 1}^K {Z_j } |x - R_j |^{ - 1}) withZ j ≧0,e ?2=137.04.H is bounded below if and only ife 2 Z j ≦2/π allj. Assuming this condition, the system is unstable whene 2∑Z j >2/π in the sense thatE 0=inf spec(H)→?∞ as the R j →0, allj. We prove that the nuclear Coulomb repulsion more than restores stability; namely (E_0 + 0.069e^2 sumlimits_{i< j} {Z_i Z_j } |R_i - R_j |^{ - 1} geqq 0) . We also show thatE 0 is an increasing function of the internuclear distances |R i ?R j |. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|