Photochemical synthesis, conformational analysis, and transformation of [60]fullerene-o-quinodimethane adducts bearing a hydroxy group |
| |
Authors: | Nakamura Yosuke O-Kawa Kyoji Minami Satoshi Ogawa Toshio Tobita Seiji Nishimura Jun |
| |
Institution: | Department of Chemistry, Gunma University, Tenjin-cho, Kiryu, Gunma 376-8515, Japan. |
| |
Abstract: | The photochemical reactions of 60]fullerene with various aromatic aldehydes or ketones 1a-n carrying an alkyl group at the ortho position were examined. Some of them afforded stable o-quinodimethane adducts 2 with a hydroxy group attached to the cyclohexene ring. The adducts 2 were found to adopt one or both of two conformers A and E, which possess pseudoaxial and pseudoequatorial hydroxy groups, respectively. The conformer ratios depended remarkably on the substituents attached to the aromatic nucleus and the cyclohexene ring. The dynamic behavior of 2 was also investigated by the VT-NMR technique. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|