Z-selective homodimerization of terminal olefins with a ruthenium metathesis catalyst |
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| Authors: | Keitz Benjamin K Endo Koji Herbert Myles B Grubbs Robert H |
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| Institution: | Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125, USA. |
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| Abstract: | The cross-metathesis of terminal olefins using a novel ruthenium catalyst results in excellent selectivity for the Z-olefin homodimer. The reaction was found to tolerate a large number of functional groups, solvents, and temperatures while maintaining excellent Z-selectivity, even at high reaction conversions. |
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