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Mesomorphic Characteristics of Induced Chiral Nematic Phase of [Smectic LCP,PS(4BC/DM)/Nematic LC,E7/Chiral Dopant,CB-15]-Ternary Composite System
引用本文:YANG Huai 1,2**,Hirotsugu Kikuchi 2,CHENG Xin Fang 1,Tisato Kajiyama 2 ( 1Institute of Materials Science,Jilin University,Changchun,130023) ( 2Department of Chemical Science and Technology,Faculty of Engineering,Kyushu Unive. Mesomorphic Characteristics of Induced Chiral Nematic Phase of [Smectic LCP,PS(4BC/DM)/Nematic LC,E7/Chiral Dopant,CB-15]-Ternary Composite System[J]. 高等学校化学研究, 1997, 13(2): 163-168
作者姓名:YANG Huai 1  2**  Hirotsugu Kikuchi 2  CHENG Xin Fang 1  Tisato Kajiyama 2 ( 1Institute of Materials Science  Jilin University  Changchun  130023) ( 2Department of Chemical Science and Technology  Faculty of Engineering  Kyushu Unive
作者单位:YANG Huai 1,2**,Hirotsugu Kikuchi 2,CHENG Xin Fang 1,Tisato Kajiyama 2 ( 1Institute of Materials Science,Jilin University,Changchun,130023
基金项目:Supported by the National Natural Science Foundation of China.
摘    要:MesomorphicCharacteristicsofInducedChiralNematicPhaseof[SmecticLCP,PS(4BC/DM)/NematicLC,E7/ChiralDopant,CB┐15]┐TernaryComposi...

收稿时间:1997-03-26

Mesomorphic Characteristics of Induced Chiral Nematic Phase of [Smectic LCP, PS(4BC/DM) /Nematic LC, E7/Chiral Dopant, CB 15] Ternary Composite System *
YANG Huai ,,Hirotsugu Kikuchi ,CHENG Xin Fang ,Tisato Kajiyama. Mesomorphic Characteristics of Induced Chiral Nematic Phase of [Smectic LCP, PS(4BC/DM) /Nematic LC, E7/Chiral Dopant, CB 15] Ternary Composite System *[J]. Chemical Research in Chinese University, 1997, 13(2): 163-168
Authors:YANG Huai     Hirotsugu Kikuchi   CHENG Xin Fang   Tisato Kajiyama
Affiliation:1. Institute of Materials Science, Jilin University, Changchun 130023;
2. Department of Chemical Science and Technology, Faculty of Engineering, Kyushu University 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812, Japan
Abstract:The phase transition behavior and aggregating states of [smectic LCP, PS(4BC/DM)/nematic LC, E7/chiral dopant, CB 15] ternary composite system were investigated on the basis of differential scanning calorimetry (DSC) measurement, polarizing optical microscopy (POM) observation and wide angle X ray diffraction (WAXD) patterns. It was demonstrated that if the weight ratio of the chiral dopant was fixed as 4.8wt%, an induced chiral nematic (N *) phase existed in the ternary system when PS(4BC/DM) ratio was below 47.6 wt%. Moreover, smectic like long range ordering appeared in the induced N * phase in a certain temperature range just above the smectic A(S A) N * phase transition when PS(4BC/DM) ratio was between 19.1wt% and 47.6wt%.
Keywords:Mesomorphic   Induced chiral nematic phase   Dopant
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