Study of the 1-chloro-2,4-dinitrobenzene + oh- reaction in tetradecyltrimethylammonium bromide aqueous micellar solutions |
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| Authors: | María del Mar Graciani Amalia Rodríguez María Mu?oz and María Luisa Moyá |
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| Institution: | (1) Departamento de Química Física, Universidad de Sevilla, C/ Profesor García González s/n, 41012 Sevilla, Spain |
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| Abstract: | The 1-chloro-2,4-dinitrobenzene + OH- reaction was studied in tetradecyltrimethylammonium bromide aqueous micellar solutions. Influence of changes in surfactant]
as well as in NaOH] on the observed rate constant were rationalized by using pseudophase kinetic models. At high hydroxide
ions concentration an additional pathway across the micellar boundary had to be considered.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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| Keywords: | micelles TTAB 1-chloro-2 Kinetics 4-dinitrobenzene |
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