| Synthesis and Crystal Structure of a New Oxovanadium（V） Multicomponent Complex with Acylhydrazone and Benzoylhydrazine |
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| 引用本文： | 周荫庄 陈瑞金 屠淑洁 鲁晓明. Synthesis and Crystal Structure of a New Oxovanadium（V） Multicomponent Complex with Acylhydrazone and Benzoylhydrazine[J]. 中国化学, 2006, 24(1): 153-156. DOI: 10.1002/cjoc.200690014 |
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| 作者姓名： | 周荫庄 陈瑞金 屠淑洁 鲁晓明 |
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| 作者单位： | Department of Chemistry, Capital Normal University, BeUing 100037, China |
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| 基金项目： | Project supported by the Scientific Research Common Program of Beijing Municipal Commission of Education of China （No. KM20051028005）. |
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| 摘 要： | A new oxovanadium（V） complex with the mixed ligand of 2-oxopropionic acid benzoylhydrazone （C10H10N2O3） and benzoylhydrazine （C7H8N2O）, VO（C7H7N2O）（C10H9N2O3）, has been synthesized. Its structure was determined by single crystal X-ray diffraction analysis. The crystal belongs to monoclinic system with space group P21/n and cell parameters： a=1.1136（4） nm, b=0.6217（2） nm, c=2.6038（9） nm, β=97.182（6）°, V= 1.7887（11） nm^3, Z=4, F（000）=836, Mr=407.28, Dc= 1.512 g/cm^3,μ （Mo Kα） =0.592 mm^-1, R1 =0.0445, wR2= 0.1203. Vanadium atom is 6-coordinated by carboxyl and carbonyl O atoms and N atom of one tridentate C10H10N2O3 to form two stable five-membered rings with the same edge, and the other coordinated atoms of N and O come from one bidentate benzoylhydrazine C7H8N2O. The title complex has a six-coordinated V center [VO（N2O3）] with a distorted octahedral arrangement. In the crystal lattice, there are hydrogen bonding interactions between two molecules.
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| 关 键 词： | 氧络钒 合成方法 晶体结构 苯甲酰肼 |
| 收稿时间： | 2004-12-16 |
| 修稿时间： | 2004-12-162005-09-28 |
Synthesis and Crystal Structure of a New Oxovanadium(V)Multicomponent Complex with Acylhydrazone and Benzoylhydrazine |
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| Zhou YinZhuang;Chen RuiJin;Tu ShuJie;Lu XiaoMing. Synthesis and Crystal Structure of a New Oxovanadium(V)Multicomponent Complex with Acylhydrazone and Benzoylhydrazine[J]. Chinese Journal of Chemistry, 2006, 24(1): 153-156. DOI: 10.1002/cjoc.200690014 |
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| Authors: | Zhou YinZhuang Chen RuiJin Tu ShuJie Lu XiaoMing |
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| Abstract: | A new oxovanadium(V) complexwith the mixed ligand of 2‐oxopropionic acid benzoylhydrazone (C10H10N2O3) and benzoylhydrazine (C7H8N2O), VO(C7H7N2O)(C10H9N2O3), has been synthesized. Its structure was determined by single crystal X‐ray diffraction analysis. The crystal belongs to monoclinic system with space group P21/n and cell parameters: a=1.1136(4) nm, b=0.6217(2) nm,c=2.6038(9) nm,β=97.182(6)(, V=1.7887(11) nm3, Z=4, F(000)=836, Mr?407.28, Dc=1.512 g/cm3, μ(Mo Kα)=0.592 mm?1, R1=0.0445, wR2=0.1203. Vanadium atom is 6‐coordinated by carboxyl and carbonyl O atoms and N atom of one tridentate C10H10N2O3 to form two stable five‐membered rings with the same edge, and the other coordinated atoms of N and O come from one bidentate benzoylhydrazine C7H8N2O. The title complex has a six‐coordinated V center [VO(N2O3)] with a distorted octahedral arrangement. In the crystal lattice, there are hydrogen bonding interactions between two molecules. |
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| Keywords: | oxovanadium(V) complex 2‐oxopropionic acid benzoylhydrazone benzoylhydrazine synthesis crystal structure |
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