Synthesis of tungsten oxides with cellular structure

Being exposed to hydrochloric acid vapor, solutions of a surfactant and sodium tungstate form tungstic-acid-based materials with a structure representing a system of interpenetrating hollow spheres 2–8 μm in diameter constructed from lamellar H₂WO₄ crystals with a thickness of 80–200 nm. The reduction of the tungstic-acid-based material with hydrogen gives rise to the formation of a material based on tungsten(IV) oxide (WO₂), which retains the initial structure. The adsorption capacity of the tungstic-acid-based materials is determined with respect to benzene. The specific surface area of the obtained materials is 60–110 m²/g.