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Chemical reactions as dynamical systems on the interval
Authors:L Rondoni  R F Streater
Institution:(1) Center for Transport Theory and Mathematical Physics, Virginia Polytechnic Institute, USA;(2) State University, 24061 Blacksburg, Virginia
Abstract:We consider the most general chemical reaction of the typen 1 A 1+...+n N A N rlharm 1 B 1+...+m M B M whereN,Mges1,n 1,...,n N andm 1,...,m M are positive integers defining the stoichiometry, andA 1,...,A N andB 1,...,B M are the names of chemicals or ions. We assume that sum i=1 N ni=sum j=1 M mj. The time evolution of the concentrations is given by the law of mass action and leads to a dynamical system (with discrete or continuous time) which is governed by a polynomial map of the interval B, C], where Bges0 and Cles1. We define the physically meaningful range for the parameters of the map, and we show that, within such a range, the map has a unique fixed point, which is stable and a global attractor, with the exception of one particular case, where bifurcation is observed.
Keywords:Boltzmann  chemical kinetics  stability  chaos  entropy
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