| Ce掺杂对La1-xCexCoO3催化剂的结构和催化氧化性能的影响 |
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| 引用本文： | BULGAN G.,梁淑惠,滕飞,姚文清,朱永法.Ce掺杂对La1-xCexCoO3催化剂的结构和催化氧化性能的影响[J].物理化学学报,2008,24(2):205-210. |
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| 作者姓名： | BULGAN G. 梁淑惠 滕飞 姚文清 朱永法 |
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| 作者单位： | Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China |
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| 摘 要： | 采用非晶态配合物的方法合成了La1-xCexCoO3(x=0、0.05、0.1、0.2、0.3)催化剂, 并采用X射线衍射(XRD)、透射电镜(TEM)和比表面测定仪(BET)等手段对催化剂的微观结构进行了研究. 揭示了Ce掺杂对催化剂的钙钛矿结构, CO催化氧化以及催化氧化发光性能的影响规律. 结果表明, 在Ce4+掺杂部分取代La3+后, 催化剂形成了镧不足的La1-xCeyφx-yCoO3(φ是A位离子空位)钙钛矿相以及CeO2和Co3O4物相. 与LaCoO3催化剂相比, x=0.1催化剂的CO催化氧化活性最高(T100%=290 ℃). La1-xCexCoO3催化剂对CO催化氧化发光的响应与其催化活性密切相关.
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| 关 键 词： | 非晶态配合物 钙钛矿型催化剂 铈掺杂 催化发光 催化氧化 CO |
| 收稿时间： | 2007-07-02 |
| 修稿时间： | 2007-11-13 |
Effect of Ce Doping on the Structure and Catalytic Activity of La1-xCexCoO3 Catalysts |
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| BULGAN G.,LIANG Shu-Hui,TENG Fei,YAO Wen-Qing,ZHU Yong-Fa.Effect of Ce Doping on the Structure and Catalytic Activity of La1-xCexCoO3 Catalysts[J].Acta Physico-Chimica Sinica,2008,24(2):205-210. |
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| Authors: | BULGAN G LIANG Shu-Hui TENG Fei YAO Wen-Qing ZHU Yong-Fa |
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| Institution: | Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China |
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| Abstract: | La1-xCexCoO3 (x=0, 0.05, 0.1, 0.2, 0.3) catalysts were synthesized by amorphous heteronuclear complexing method. The catalysts were characterized by XRD, TEM, and N2 adsorption isotherms. The cataluminescence (CTL) response to CO and the activities in the oxidation of CO over the catalysts were investigated. Results showed that La1-xCeyφx-yCoO3 perovskite with lanthanumdeficiency, CeO2 and CO3O4 phases were formed after La3+ was substituted with Ce4+ in the catalyst. Compared with LaCoO3 catalyst, the catalyst with x=0.1 showed the highest activity for CO oxidation (T100%=290 ℃). The CTL result is well consistent with the order of CO catalytic activity over La1-xCexCoO3 catalysts. |
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| Keywords: | Amorphous heteronuclear complex Perovskite type catalyst Ce dopant Cataluminescence Catalytic oxidation CO |
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