Stabilizing effect of 1,1,5-trihydroperfluoropentanol on photochemical degradation of polycaproamide |
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Authors: | I. A. Novakov N. A. Storozhakova V. B. Ivanov V. V. Priimak |
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Affiliation: | (1) Volgograd State Technical University, pr. Lenina 28, Volgograd, 400131, Russia;(2) Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia |
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Abstract: | The effect of fluorinated alcohols on the photochemical degradation of polycaproamide was studied. It was shown that, even when a small amount (0.035 wt %) of 1,1,5-trihydroperfluoropentanol is added, the rate of photodegradation of polyamide fibers decreases. Electron microscopic examination showed that, in the presence of the fluorinated alcohol, the test fibers are characterized by a reduced number of defects. The simultaneous introduction of microquantities of 1,1,5-trihydroperfluoropentanol and N,N-bis(2,2,6,6-tetramethyl-4-piperidinyl) 1,3-benzenedicarbamide is responsible for the synergistic photostabilizing effect. |
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