Effects of Photocatalyst Pretreatment on the Rate of Mineralisation of a Fungicide |
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Authors: | John Nettleton-Hammond and Mounir A Malati |
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Affiliation: | (1) Zeneca Agrochemicals, Yalding, Maidstone, Kent, ME18 6HN, UK;(2) Mid-Kent College of Higher and Further Education, Chatham, Kent, ME5 9UQ, UK |
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Abstract: | The fungicide Flutriafol was mineralised on irradiation of its aqueous solution, in which anatase P25 was suspended, with a medium pressure mercury lamp under an air stream. The half-time of reaction, t1/2, i.e. the time at which the total organic carbon of the solution was halved, decreased in the series of P25 loaded with RuO2>Pt>Ag>MnO2. Heating P25 at 500°C for 3 h reduced t1/2 compared to bare, unheated P25. |
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Keywords: | Titania photocatalyst metallised titania metal oxide/titania t1/2 of mineralisation |
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