Ionic Solvation in Aqueous and Nonaqueous Solutions |
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Authors: | Hitoshi Ohtaki |
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Affiliation: | (1) Department of Physics and Postgraduate Institute of Science, University of Peradeniya, Peradeniya, Sri Lanka;(2) Department of Chemistry, Technical University of Denmark, DK-2800 Lyngby, Denmark |
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Abstract: | The history of studies on ionic solvation is briefly reviewed, and structural and dynamic properties of solvated ions in aqueous and nonaqueous solutions are discussed. An emphasis is placed on ionic solvation in nonaqueous mixed solvents in which preferential solvation of ions takes place. A new parameter for expressing the degree of preferential solvation of an ion is proposed. |
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